Adhesion and Adhesives: Fundamental and Applied Aspects

This book is the second volume in the series "Contact Angle, Wettability and Adhesion." The premier volume was published in 2013. Even a cursory glance at the literature show that in recent years the interest in understanding and controlling wetting behavior has grown exponentially. Currently, there is tremendous research activity in rendering surfaces superhydrophobic, superhydrophilic, superoleophobic, superoleophilic, omniphobic and omniphilic because of their applications in many technologically important fields. Also the durability or robustness of materials with such super" characteristics is extremely significant, as well as the utilization of "green" (biobased) materials to obtain such surfaces. This book containing 19 articles reflects more recent developments in certain areas covered in its predecessor volume as well as it includes some topics which were not covered before. Concomitantly, this book provides a medium to keep abreast of the latest research activity and developments in the arena of contact angle, wettability and adhesion. The topics discussed include: Understanding of wetting hysteresis, fabrication of superhydrophobic materials, plasma treatment to achieve superhydrophilic surfaces, highly liquid repellent textiles, modification of paper surfaces to control liquid wetting and adhesion, Cheerios effect and its control, engineering materials with superwettability, laser ablation to create micro/nano-patterned surfaces, liquid repellent amorphous carbon nanoparticle networks, mechanical durability of liquid repellent surfaces, wetting of solid walls and spontaneous capillary flow, relationship between roughness and oleophilicity, superhydrophobic and superoleophobic green materials, computational analysis of wetting on hydrophobic surfaces: application to self-cleaning mechanisms, bubble adhesion to superhydrophilic surfaces, surface free energy of superhydrophobic materials, and role of surface free energy in pharmaceutical tablet tensile strength.

With the voluminous research being published, it is difficult, if not impossible, to stay abreast of current developments in a given area. The review articles in this book consolidate information to provide an alternative way to follow the latest research activity and developments in adhesion science and adhesives. With the ever-increasing amount of research being published, it is a Herculean task to be fully conversant with the latest research developments in any field, and the arena of adhesion and adhesives is no exception. Thus, topical review articles provide an alternate and very efficient way to stay abreast of the state-of-the-art in many subjects representing the field of adhesion science and adhesives. The 19 chapters in this Volume 6 follow the same order as the review articles originally published in RAA in the year 2020 and up to June 2021. The subjects of these 19 chapters fall in the following areas: • Adhesives and adhesive joints • Contact angle • Reinforced polymer composites • Bioadhesives • Icephobic coatings • Adhesives based on natural resources • Polymer surface modification • Superhydrophobic surfaces The topics covered include: hot-melt adhesives; adhesively-bonded spar-wingskin joints; contact angle hysteresis; fiber/matrix adhesion in reinforced thermoplastic composites; bioadhesives in biomedical applications; mucoadhesive pellets for drug delivery applications; bio-inspired icephobic coatings; wood adhesives based on natural resources; adhesion in biocomposites; vacuum UV surface photo-oxidation of polymers and other materials; vitrimers and their relevance to adhesives; superhydrophobic surfaces by microtexturing; structural acrylic adhesives; mechanically durable water-repellent surfaces; mussel-inspired underwater adhesives; and cold atmospheric pressure plasma technology for modifying polymers. Audience This book will be valuable and useful to researchers and technologists in materials science, nanotechnology, physics, surface and colloid chemistry in multiple disciplines in academia, industry, various research institutes and other organizations.

The topic of wettabilty is extremely important from both fundamental and applied aspects. The applications of wettability range from self-cleaning windows to micro- and nanofluidics. This book represents the cumulative wisdom of a contingent of world-class (researchers engaged in the domain of wettability. In the last few years there has been tremendous interest in the "Lotus Leaf Effect" and in understanding its mechanism and how to replicate this effect for myriad applications. The topics of superhydrophobicity, omniphobicity and superhydrophilicity are of much contemporary interest and these are covered in depth in this book.

The book provides essential insights into the critical role of adhesive bonding in maximizing the value of wood products, equipping both students and industry professionals with the knowledge necessary to enhance production processes and improve product performance. Adhesive bonding of wood is a key factor in the efficient utilization of wood for the production of value-added wood products, such as wood-based panels. The production of wood-based panels requires high-performance bonds between wood adherends and the properties of these wooden products are largely determined by the type and performance of the adhesive used. Technology of Adhesives and Wood-Based Panels comprehensively covers wood-based panels, focusing on the technologies behind their raw materials and their production. Journey through the production process: starting with the raw materials, then application of adhesives onto the wood's surfaces, pressing the mat to the board, and curing or solidifying the adhesive. Finally, this journey will culminate in an investigation of the properties of the bondline in wood-based panels. This volume explores important concepts, including the influence of wood materials and surface on wood bonding, the performance of wood-based panels, the production technology of panels, and the behavior of adhesives when applied to wood surfaces, making it a valuable resource to industry professionals and students alike. Readers will find that this book: • Introduces wood adhesives and their chemistry and applications; • Comprehensively covers the technology of wood-based panels; • Explores connections for properties and performance between adhesives and bonded products; • Provides recent developments in wood adhesives and wood-based panels. Audience Engineers, chemists, scientists, researchers, students, production managers and technologists in the wood, wood-based panel, and adhesive industries.

The book provides a comprehensive and easily accessible reference source covering all important aspects of particle adhesion and removal. The core objective is to cover both fundamental and applied aspects of particle adhesion and removal with emphasis on recent developments. Among the topics to be covered include: 1. Fundamentals of surface forces in particle adhesion and removal. 2. Mechanisms of particle adhesion and removal. 3. Experimental methods (e.g., AFM, SFA, SFM, IFM, etc.) to understand particle-particle and particle-substrate interactions. 4. Mechanics of adhesion of micro-and nanoscale particles. 5. Various factors affecting particle adhesion to a variety of substrates. 6. Surface modification techniques to modulate particle adhesion. 7. Various cleaning methods (both wet & dry) for particle removal. 8. Relevance of particle adhesion in a host of technologies ranging from simple to ultra-sophisticated.

This important and unique book comprises 12 chapters divided into three parts examining the fundamental aspects, bioadhesive formulations, and drug delivery applications. Understanding the phenomenon of bioadhesion i.e., its theories or mechanism(s) are of critical importance in developing optimum bioadhesive polymers (used in bioadhesives). Such bioadhesive polymers are the key for exhibiting the process of bioadhesion, controlled/sustained release of drugs, and drug targeting. The use of bioadhesives restricts the delivery system to the site of interest and thus offers a useful and efficient technique for targeting a drug to the desired location for a prolonged duration. This book addresses the various relevant aspects of bioadhesives in drug delivery in an easily accessible and unified manner. The book containing 12 chapters written by eminent researchers from many parts of the globe is divided into three parts: Part 1: Fundamental Aspects; Part 2: Bioadhesive Formulations; Part 3: Drug Delivery Applications. The topics covered include: Theories and mechanisms of bioadhesion; bioadhesive polymers for drug delivery applications; methods for characterization of bioadhesiveness of drug delivery systems; bioadhesive films and drug delivery applications; bioadhesive nanoparticles; bioadhesive hydrogels and applications; ocular biodhesive drug delivery systems; buccal bioadhesive drug delivery systems; gastrointestinal bioadhesive drug delivery systems; nasal bioadhesive drug delivery systems; vaginal drug delivery systems; pulmonary bioadhesive drug delivery systems.

An indispensable volume detailing the current and potential applications of atmospheric pressure plasma treatment by experts practicing in fields around the world. Polymers are used in a wide variety of industries to fabricate legions of products because of their many desirable traits. However, polymers in general (and polyolefins, in particular) are innately not very adhesionable because of the absence of polar or reactive groups on their surfaces and concomitant low surface energy. Surface treatment of polymers, however, is essential to impart reactive chemical groups on their surfaces to enhance their adhesion characteristic. Proper surface treatment can endow polymers with improved adhesion without affecting the bulk properties. A plethora of techniques (ranging from wet to dry, simple to sophisticated, vacuum to non-vacuum) for polymer surface modification have been documented in the literature but the Atmospheric Pressure Plasma (APP) treatment has attracted much attention because it offers many advantages vis-a-vis other techniques, namely uniform treatment, continuous operation, no need for vacuum, simplicity, low cost, no environmental or disposal concern, and applicability to large area samples. Although the emphasis in this book is on the utility of APP treatment for enhancement of polymer adhesion, APP is also applicable and effective to modulate many other surface properties of polymers: superhydrophilicity, superhydrophobicity, anti-fouling, anti-fogging, anti-icing, cell adhesion, biocompatibility, tribological behavior, etc. The key features of “Atmospheric Pressure Plasma Treatment of Polymers”: • Address design and functions of various types of reactors • Bring out current and potential applications of APP treatment • Represent the cumulative wisdom of many key academic and industry researchers actively engaged in this key and enabling technology

The book details the recent and exciting developments on various fronts in the textile field with regard to novel and innovative functionalities, as well as their applications in various industries. Technical textiles are used in various industries for a host of purposes and applications. Recent developments in novel and innovative functionalities to textiles include easy-to-clean or dirt-repellent, flame retardancy, anti-bacterial, and fog-harvesting properties. Textiles for electronics based on graphene, CNTs and other nanomaterials, conductive textiles, textiles for sensor function, textile-fixed catalysts, textiles for batteries and energy storage, textiles as substrates for tissue engineering, and textiles for O/W separation are prevalent as well. All this development has been made possible through adopting novel ways for finishing textiles, e.g., by appropriate surface modification techniques, and utilizing biomimetic concepts borrowed from nature. This unique book is divided into four parts: Part 1: Recent Developments/Current Challenges in Textile Finishing; Part 2: Surface Modification Techniques for Textiles; Part 3: Innovative Functionalities of Textiles; Part 4: Fiber-Reinforced Composites. The topics covered include: Antimicrobial textile finishes; flame retardant textile finishing; "self-cleaning" or easy-to-clean textiles; metallization of textiles; atmospheric pressure plasma, and UV-based photochemical surface modification of textiles; tunable wettability of textiles; 3D textile structures for fog harvesting; textile-fixed catalysts; medical textiles as substrates for tissue engineering; and fiber-reinforced "green" or "greener" biocomposites and the relevance of fiber/matrix adhesion.

Unique and comprehensive book edited by acknowledged leaders on biobased adhesives that will replace petroleum-based adhesives. This book contains 23 chapters covering the various ramifications of biobased adhesives. The chapters are written by world-class scientists and technologists actively involved in the arena of biobased adhesives. The book is divided into three parts: Part 1: Fundamental Aspects; Part 2: Classes of Biobased Adhesives; and Part 3: Applications of Biobased Adhesives. Topics covered include: an introduction to biobased adhesives; adhesion theories and adhesion and surface issues with biobased adhesives; chemistry of adhesives; biorefinery products as biobased raw materials for adhesives; naturally aldehyde-based thermosetting resins; natural crosslinkers; curing and adhesive bond strength development in biobased adhesives; mimicking nature; bio-inspired adhesives; protein adhesives; carbohydrates as adhesives; natural polymer-based adhesives; epoxy adhesives from natural materials; biobased polyurethane adhesives; nanocellulose-modified adhesives; debondable, recyclable, and biodegradable biobased adhesives; 5-Hydroxymethylfurfural-based adhesives; adhesive precursors from tree-derived naval stores; and applications in various diverse arenas such as wood bonding, controlled drug delivery, and wearable bioelectronics. Audience This book will interest materials scientists, adhesionists, polymer chemists, marine biologists, food and agriculture scientists, and environmentalists. R&D personnel in a slew of wide-ranging industries such as aviation, shipbuilding, railway, automotive, packaging, construction, wood bonding, and composites should find this book a repository of current and much-needed information.

Keep up-to-date with the latest on adhesion and adhesives from an expert group of worldwide authors. The book series "Progress in Adhesion and Adhesives" was conceived as an annual publication and the premier volume made its debut in 2015. The series has been well-received as it is unique and provides substantive and curated review chapters on subjects that touch many disciplines. The current book contains nine chapters on topics that include multi-component theories in surface thermodynamics and adhesion science; plasma-deposited polymer layers as adhesion promotors; functional interlayers to control interfacial adhesion in reinforced polymer composites; hydrophobic materials, and coatings from natural sources; mechanics of ice adhesion; epoxy adhesives technology: latest developments and trends; hot-melt adhesives for automobile assembly; lifetime estimation of thermostat adhesives by physical and chemical aging processes; and nondestructive evaluation and condition monitoring of adhesive joints. Audience The volume will appeal to adhesionists, adhesive technologists, polymer scientists, materials scientists, and those involved/interested in adhesive bonding, plasma polymerization, adhesion in polymer composites, durability and testing of adhesive joints, materials from natural sources, and ice adhesion and mitigation.

The book provides a unique overview on laser techniques and applications for the purpose of improving adhesion by altering surface chemistry and topography/morphology of the substrate. It details laser surface modification techniques for a wide range of industrially relevant materials (plastics, metals, ceramics, composites) with the aim to improve and enhance their adhesion to other materials. The joining of different materials is of critical importance in the fabrication of many and varied products.

ADHESIVES IN BIOMEDICAL APPLICATIONS Uniquely provides up-to-date and comprehensive information on adhesives in biomedical applications in an easily accessible form. Adhesives are gaining popularity in many and varied biomedical applications as they are being used as a replacement for sutures and staples, which have the disadvantages such as scarring, infection, keloid formation, poor skin healing, or hernia in the case of abdominal sutures. On the other hand, adhesives dramatically reduce healthcare costs, significantly reduce time spent in surgery, curb the risks of bleeding, and are generally easy to use. Adhesives also find their use in diagnostic imaging, various biomedical devices, dental adhesives, dermal adhesives, etc. Adhesives in Biomedical Applications contains eleven chapters and is divided into two parts: Part 1: General Topics; and Part 2: Specific Adhesives, Characteristics, and Applications. Topics covered include: historical developments of various adhesives for biomedical applications; global industry development and analysis of adhesives for biomedical applications; biomedical adhesives; bioadhesion: fundamentals and mechanisms; fibrin glue; herbal bioactives-based mucoadhesive drug delivery systems; adhesive hydrogels; adhesives in dermal patches; medical adhesives from extracted mussel adhesive proteins; dental adhesives; and the role of adhesive-based systems for diagnostic imaging and theranostic applications. Audience The book will be used by adhesionists, adhesive technologists, polymer scientists, materials scientists, as well as those involved with biomedical devices and bioimplants such as medical doctors, surgeons, cosmetologists, as well as engineers in the pharmaceutical industry.

This comprehensive book will provide both fundamental and applied aspects of adhesion pertaining to microelectronics in a single and easily accessible source. Among the topics to be covered include; • Various theories or mechanisms of adhesion • Surface (physical or chemical) characterization of materials as it pertains to adhesion • Surface cleaning as it pertains to adhesion • Ways to improve adhesion • Unraveling of interfacial interactions using an array of pertinent techniques • Characterization of interfaces / interphases • Polymer-polymer adhesion • Metal-polymer adhesion (metallized polymers) • Polymer adhesion to various substrates • Adhesion of thin films • Adhesion of underfills • Adhesion of molding compounds • Adhesion of different dielectric materials • Delamination and reliability issues in packaged devices • Interface mechanics and crack propagation • Adhesion measurement of thin films and coatings

The only book to cover adhesion in pharmaceutical, biomedical and dental fields The phenomenon of adhesion is of cardinal importance in the pharmaceutical, biomedical and dental fields. A few eclectic examples will suffice to underscore the importance/relevance of adhesion in these three areas. For example, the adhesion between powdered solids is of crucial importance in tablet manufacture. The interaction between biodevices (e.g., stents, bio-implants) and body environment dictates the performance of such devices, and there is burgeoning research activity in modifying the surfaces of such implements to render them compatible with bodily components. In the field of dentistry, the modern trend is to shift from retaining of restorative materials by mechanical interlocking to adhesive bonding. The book contains 15 chapters written by internationally-renowned subject matter experts and is divided into four parts: Part 1: General Topics, Part 2: Adhesion in Pharmaceutical Field, Part 3: Adhesion in Biomedical Field, and Part 4: Adhesion in Dental Field. The topics covered include: Theories or mechanisms of adhesion, wettability of powders, role of surface free energy in tablet strength and powder flow behavior, mucoadhesive polymers for drug delivery systems, transdermal patches, skin adhesion in long-wear cosmetics, factors affecting microbial adhesion, biofouling and ways to mitigate it, adhesion of coatings on surgical tools and bio-implants, adhesion in fabrication of microarrays in clinical diagnostics, antibacterial polymers for dental adhesives and composites, evolution of dental adhesives, and testing of dental adhesive joints.

Significant research has been done in polymeric nanocomposites and progress has been made in understanding nanofiller-polymer interface and interphase and their relation to nanocomposite properties. However, the information is scattered in many different publication media. This is the first book that consolidates the current knowledge on understanding, characterization and tailoring interfacial interactions between nanofillers and polymers by bringing together leading researchers and experts in this field to present their cutting-edge research. Eleven chapters authored by senior subject specialists cover topics including: • Thermodynamic mechanisms governing nanofiller dispersion, engineering of interphase with nanofillers • Role of interphase in governing the mechanical, electrical, thermal and other functional properties of nanocomposites, characterization and modelling of the interphase • Effects of crystallization on the interface, chemical and physical techniques for surface modification of nanocellulose reinforcements • Electro-micromechanical and nanoindentation techniques for interface evaluation, molecular dynamics (MD) simulations to quantify filler-matrix adhesion and nanocomposite mechanical properties.

The acronym Laser is derived from Light Amplification by Stimulated Emission of Radiation. With the advent of the ruby laser in 1960, there has been tremendous research activity in developing novel, more versatile and more efficient laser sources or devices, as lasers applications are ubiquitous. Today, lasers are used in many areas of human endeavor and are routinely employed in a host of diverse fields: various branches of engineering, microelectronics, biomedical, medicine, dentistry, surgery, surface modification, to name just a few. In this book (containing 10 chapters) we have focused on application of lasers in adhesion and related areas. The topics covered include: • Topographical modification of polymers and metals by laser ablation to create superhydrophobic surfaces. • Non-ablative laser surface modification. • Laser surface modification to enhance adhesion. • Laser surface engineering of materials to modulate their wetting behavior. • Laser surface modification in dentistry. • Laser polymer welding. • Laser based adhesion testing technique to measure thin film-substrate interface toughness. • Laser surface removal of hard thin ceramic coatings. • Laser removal of particles from surfaces. • Laser induced thin film debonding for micro-device fabrication applications.

With the ever-increasing amount of research being published it is a Herculean task to be fully conversant with the latest research developments in any field, and the arena of adhesion and adhesives is no exception. Thus, topical review articles provide an alternate and very efficient way to stay abreast of the state-of-the-art in may subjects representing the field of adhesion science and adhesives. Based on the success and the warm reception accorded to the premier volume in this series "Progress in Adhesion and Adhesives" (containing the review articles published in Volume 2 (2014) of the journal Reviews of Adhesion and Adhesives (RAA)), volume 2 comprises 14 review articles published in Volume 4 (2016) of RAA. The subjects of these 14 reviews fall into the following general areas: 1. Surface modification of polymers for a variety of purposes. 2. Adhesion aspects in reinforced composites 3. Thin films/coatings and their adhesion measurement 4. Bioadhesion and bio-implants 5. Adhesives and adhesive joints 6. General adhesion aspects The topics covered include: surface modification of natural fibers for reinforced polymer composites; adhesion of submicrometer thin metals films; surface treatments to modulate bioadhesion; hot-melt adhesives from renewable resources; particulate-polymer composites; functionally graded adhesively bonded joints; fabrication of nano-biodevices; effects of particulates on contact angles, thermal stresses in adhesively bonded joints and ways to mitigate these; laser-assisted electroless metallization of polymer materials; adhesion measurement of coatings on biodevices/implants; cyanoacrylate adhesives; and adhesion of green flame retardant coatings onto polyolefins.

The book comprehensively charts a way for industry to employ adhesively bonded joints to make systems more efficient and cost-effective. Adhesively bonded systems have found applications in a wide spectrum of industries (e.g., aerospace, electronics, construction, ship building, biomedical, etc.) for a variety of purposes. Emerging adhesive materials with improved mechanical properties have allowed adhesion strength approaching that of the bonded materials themselves. Due to advances in adhesive materials and the many potential merits that adhesive bonding offers, adhesive bonding has replaced other joining methods in many applications. Containing nine articles written by world-renowned experts, the book deals with the advances in theoretical and computational modeling as well as the design and experimental aspects of adhesively bonded structural systems. Stress analysis and strength prediction of adhesively bonded structural systems, considering a range of material models under a variety of loading conditions, are discussed. Finite element modeling using macro-elements is elaborated on. Recent developments in modeling and experimental aspects of bonded systems with graded adhesive layers and dual adhesives are described. Simulation of progressive damage in bonded joints is addressed. A novel vibration-based approach to detect disbonding and delamination in composite joints is also discussed. The book is central to a range of engineers including mechanical, reliability, construction and surface engineers as well as materials scientists who are engaged in the mechanics of structural adhesive joints. Industries that will use this book include aerospace, electronics, biomedical, automotive, ship building, and construction.

This unique book presents ways to mitigate the disastrous effects of snow/ice accumulation and discusses the mechanisms of new coatings deicing technologies. The strategies currently used to combat ice accumulation problems involve chemical, mechanical or electrical approaches. These are expensive and labor intensive, and the use of chemicals raises serious environmental concerns. The availability of truly icephobic surfaces or coatings will be a big boon in preventing the devastating effects of ice accumulation. Currently, there is tremendous interest in harnessing nanotechnology in rendering surfaces icephobic or in devising icephobic surface materials and coatings, and all signals indicate that such interest will continue unabated in the future. As the key issue regarding icephobic materials or coatings is their durability, much effort is being spent in developing surface materials or coatings which can be effective over a long period. With the tremendous activity in this arena, there is strong hope that in the not too distant future, durable surface materials or coatings will come to fruition. This book contains 20 chapters by subject matter experts and is divided into three parts-Part 1: Fundamentals of Ice Formation and Characterization; Part 2: Ice Adhesion and Its Measurement; and Part 3: Methods to Mitigate Ice Adhesion. The topics covered include: factors influencing the formation, adhesion and friction of ice; ice nucleation on solid surfaces; physics of ice nucleation and growth on a surface; condensation frosting; defrosting properties of structured surfaces; relationship between surface free energy and ice adhesion to surfaces; metrology of ice adhesion; test methods for quantifying ice adhesion strength to surfaces; interlaboratory studies of ice adhesion strength; mechanisms of surface icing and deicing technologies; icephobicities of superhydrophobic surfaces; anti-icing using microstructured surfaces; icephobic surfaces: features and challenges; bio-inspired anti-icing surface materials; durability of anti-icing coatings; durability of icephobic coatings; bio-inspired icephobic coatings; protection from ice accretion on aircraft; and numerical modeling and its application to inflight icing.